The USEREMAIL() function takes no arguments, so USEREMAIL(Toegang[Acces]) is invalid.
USEREMAIL() produces a single value, but Toegang[Acces] produces a list of values (see Constructing a List in List Expressions and Aggregates). You can’t directly compare a singular value to a list, so Toegang[Acces] = USEREMAIL() is also invalid.
To check whether a singular value (e.g., USEREMAIL()) occur in a list of values (e.g., Toegang[Acces]), use the IN() function, like this: