It would be an awesome feature to have so admins can recover passwords that were lost when a user clears their browser history (especially in Chrome) and lose all their passwords.
A feature to help recover them so they don’t have to submit recovery passwords for a dozen or more websites that are used in their daily business
I think what you’re looking for is a password management tool, like Google’s own Google Password Manager (https://passwords.google.com) or the third-party tools like LastPass and OnePassword.
Allowing someone else to recover session cookies is not great from a security point of view—see the thread at https://www.googlecloudcommunity.com/gc/Workspace-Q-A/Account-Security-Chrome-Cookie-Hijacking-Password-Reauth-Multi/m-p/536409 for a closely-related discussion.
Hope that helps,
Ian